Responsive cyclohexane-based low-molecular-weight hydrogelators with modular architecture

Kjeld J C van Bommel; Cornelia van der Pol; Inouk Muizebelt; Arianna Friggeri; André Heeres; Auke Meetsma; Ben L Feringa; Jan van Esch

doi:10.1002/anie.200352396

Responsive cyclohexane-based low-molecular-weight hydrogelators with modular architecture

Kjeld J C van Bommel, Cornelia van der Pol, Inouk Muizebelt, Arianna Friggeri, André Heeres, Auke Meetsma, Ben L Feringa, Jan van Esch

Biobased Ingredients and Materials

Biomade Technology Foundation

Onderzoeksoutput: Article › Academic › peer review

Samenvatting

pH-sensitive gels: By using a cyclohexane-based scaffold to which various amino acid based substituents can be connected, low-molecular-weight compounds were obtained that can gelate water at very low concentrations. Their modular design (see picture: AA = amino acid(s), X = hydrophilic substituent, dark purple = hydrophobic region, light purple = hydrophilic region), allows tuning of the thermally and pH-induced reversible gel-to-sol transition of their gels.

Originele taal-2	English
Pagina's (van-tot)	1663-1667
Tijdschrift	Angewandte Chemie (International ed. in English)
Volume	43
Nummer van het tijdschrift	13
DOI's	https://doi.org/10.1002/anie.200352396
Status	Published - 19 mrt. 2004

Keywords

aminozuren

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10.1002/anie.200352396

2 Article

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Onderzoeksoutput: Article › Academic › peer review

Open Access
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Onderzoeksoutput: Article › Academic › peer review

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title = "Responsive cyclohexane-based low-molecular-weight hydrogelators with modular architecture",

abstract = "pH-sensitive gels: By using a cyclohexane-based scaffold to which various amino acid based substituents can be connected, low-molecular-weight compounds were obtained that can gelate water at very low concentrations. Their modular design (see picture: AA = amino acid(s), X = hydrophilic substituent, dark purple = hydrophobic region, light purple = hydrophilic region), allows tuning of the thermally and pH-induced reversible gel-to-sol transition of their gels.",

keywords = "crystallography, x-ray, cyclohexanes, hydrogels, hydrogen-ion concentration, models, molecular, molecular conformation, molecular weight, aminozuren",

author = "{van Bommel}, {Kjeld J C} and {van der Pol}, Cornelia and Inouk Muizebelt and Arianna Friggeri and Andr{\'e} Heeres and Auke Meetsma and Feringa, {Ben L} and {van Esch}, Jan",

year = "2004",

month = mar,

day = "19",

doi = "10.1002/anie.200352396",

language = "English",

volume = "43",

pages = "1663--1667",

journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - Responsive cyclohexane-based low-molecular-weight hydrogelators with modular architecture

AU - van Bommel, Kjeld J C

AU - van der Pol, Cornelia

AU - Muizebelt, Inouk

AU - Friggeri, Arianna

AU - Heeres, André

AU - Meetsma, Auke

AU - Feringa, Ben L

AU - van Esch, Jan

PY - 2004/3/19

Y1 - 2004/3/19

N2 - pH-sensitive gels: By using a cyclohexane-based scaffold to which various amino acid based substituents can be connected, low-molecular-weight compounds were obtained that can gelate water at very low concentrations. Their modular design (see picture: AA = amino acid(s), X = hydrophilic substituent, dark purple = hydrophobic region, light purple = hydrophilic region), allows tuning of the thermally and pH-induced reversible gel-to-sol transition of their gels.

AB - pH-sensitive gels: By using a cyclohexane-based scaffold to which various amino acid based substituents can be connected, low-molecular-weight compounds were obtained that can gelate water at very low concentrations. Their modular design (see picture: AA = amino acid(s), X = hydrophilic substituent, dark purple = hydrophobic region, light purple = hydrophilic region), allows tuning of the thermally and pH-induced reversible gel-to-sol transition of their gels.

KW - crystallography, x-ray

KW - cyclohexanes

KW - hydrogels

KW - hydrogen-ion concentration

KW - models, molecular

KW - molecular conformation

KW - molecular weight

KW - aminozuren

U2 - 10.1002/anie.200352396

DO - 10.1002/anie.200352396

M3 - Article

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EP - 1667

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 13

ER -

Responsive cyclohexane-based low-molecular-weight hydrogelators with modular architecture

Samenvatting

Keywords

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Vingerafdruk

Onderzoekersoutput

Catalytic Conversion of Free Fatty Acids to Bio-Based Aromatics: A Model Investigation Using Oleic Acid and an H-ZSM-5/Al2O3 Catalyst

GMP Compliant Synthesis of Canagliflozin, a Novel PET Tracer for the Sodium−Glucose Cotransporter 2

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