Responsive cyclohexane-based low-molecular-weight hydrogelators with modular architecture

Kjeld J C van Bommel; Cornelia van der Pol; Inouk Muizebelt; Arianna Friggeri; André Heeres; Auke Meetsma; Ben L Feringa; Jan van Esch

doi:10.1002/anie.200352396

Responsive cyclohexane-based low-molecular-weight hydrogelators with modular architecture

Kjeld J C van Bommel, Cornelia van der Pol, Inouk Muizebelt, Arianna Friggeri, André Heeres, Auke Meetsma, Ben L Feringa, Jan van Esch

Biobased Ingredients and Materials

Onderzoeksoutput: Article › Academic › peer review

Samenvatting

pH-sensitive gels: By using a cyclohexane-based scaffold to which various amino acid based substituents can be connected, low-molecular-weight compounds were obtained that can gelate water at very low concentrations. Their modular design (see picture: AA = amino acid(s), X = hydrophilic substituent, dark purple = hydrophobic region, light purple = hydrophilic region), allows tuning of the thermally and pH-induced reversible gel-to-sol transition of their gels.

Originele taal-2	English
Pagina's (van-tot)	1663-1667
Tijdschrift	Angewandte Chemie (International ed. in English)
Volume	43
Nummer van het tijdschrift	13
DOI's	https://doi.org/10.1002/anie.200352396
Status	Published - 19 mrt 2004

Keywords

aminozuren

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10.1002/anie.200352396

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Citeer dit

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abstract = "pH-sensitive gels: By using a cyclohexane-based scaffold to which various amino acid based substituents can be connected, low-molecular-weight compounds were obtained that can gelate water at very low concentrations. Their modular design (see picture: AA = amino acid(s), X = hydrophilic substituent, dark purple = hydrophobic region, light purple = hydrophilic region), allows tuning of the thermally and pH-induced reversible gel-to-sol transition of their gels.",

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Responsive cyclohexane-based low-molecular-weight hydrogelators with modular architecture. / van Bommel, Kjeld J C; van der Pol, Cornelia; Muizebelt, Inouk; Friggeri, Arianna; Heeres, André; Meetsma, Auke; Feringa, Ben L; van Esch, Jan.

In: Angewandte Chemie (International ed. in English), Vol. 43, Nr. 13, 19.03.2004, blz. 1663-1667.

Onderzoeksoutput: Article › Academic › peer review

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AU - van Bommel, Kjeld J C

AU - van der Pol, Cornelia

AU - Muizebelt, Inouk

AU - Friggeri, Arianna

AU - Heeres, André

AU - Meetsma, Auke

AU - Feringa, Ben L

AU - van Esch, Jan

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KW - crystallography, x-ray

KW - cyclohexanes

KW - hydrogels

KW - hydrogen-ion concentration

KW - models, molecular

KW - molecular conformation

KW - molecular weight

KW - aminozuren

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