Development of a modular photoreactor for the upscaling of continuous flow photochemistry

Johannes G.H. Hermens; Mathieu Lepage; Arjan Kloekhorst; Erik Keller; Ben L. Feringa; Robin Bloem; Maurice Meijer

doi:10.1039/D2RE00310D

Development of a modular photoreactor for the upscaling of continuous flow photochemistry

Johannes G.H. Hermens (First author), Mathieu Lepage, Arjan Kloekhorst, Erik Keller, Ben L. Feringa, Robin Bloem, Maurice Meijer

Stratingh Institute, University of Groningen

Onderzoeksoutput: Article › Academic › peer review

Samenvatting

The upscaling of biphasic photochemical reactions is challenging because of the inherent constraints of liquid-gas mixing and light penetration. Using semi-permeable coaxial flow chemistry within a modular photoreactor, the photooxidation of the platform chemical furfural was scaled up to produce routinely 29 gram per day of biobased building block hydroxybutenolide, a precursor to acrylate alternatives.

Originele taal-2	English
Pagina's (van-tot)	2280-2284
Aantal pagina's	5
Tijdschrift	Reaction Chemistry & Engineering
Volume	7
Nummer van het tijdschrift	11
DOI's	https://doi.org/10.1039/D2RE00310D https://doi.org/10.1039/d2re00310d
Status	Published - 28 sep. 2022

Keywords

modulaire fotoreactor
continue fotochemie
opschalen

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10.1039/D2RE00310DLicentie: Unspecified
10.1039/d2re00310dLicentie: CC BY-NC

Biobased/circular chemistry at the Hanze.
André Heeres (Speaker) & Erik Keller (Speaker)
2 jun. 2023
Activiteit: Invited talk
Biobased/circular chemistry at the Hanze
André Heeres (Speaker) & Erik Keller (Speaker)
31 mei 2023
Activiteit: Invited talk

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AU - Hermens, Johannes G.H.

AU - Lepage, Mathieu

AU - Kloekhorst, Arjan

AU - Keller, Erik

AU - Feringa, Ben L.

AU - Bloem, Robin

AU - Meijer, Maurice

PY - 2022/9/28

Y1 - 2022/9/28

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AB - The upscaling of biphasic photochemical reactions is challenging because of the inherent constraints of liquid-gas mixing and light penetration. Using semi-permeable coaxial flow chemistry within a modular photoreactor, the photooxidation of the platform chemical furfural was scaled up to produce routinely 29 gram per day of biobased building block hydroxybutenolide, a precursor to acrylate alternatives.

KW - modular photoreactor

KW - continuous flow photochemistry

KW - upscaling

KW - modulaire fotoreactor

KW - continue fotochemie

KW - opschalen

U2 - 10.1039/D2RE00310D

DO - 10.1039/D2RE00310D

M3 - Article

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SN - 2058-9883

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EP - 2284

JO - Reaction Chemistry & Engineering

JF - Reaction Chemistry & Engineering

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ER -

Development of a modular photoreactor for the upscaling of continuous flow photochemistry

Samenvatting

Keywords

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Activiteiten

Biobased/circular chemistry at the Hanze.

Biobased/circular chemistry at the Hanze

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