Allosterically driven multicomponent assembly

Pall Thordarson; Ruud G.E. Coumans; Johannes A.A.W. Elemans; Johan Visser; Paul J. Thomassen; Alan E. Rowan; Roeland J.M. Nolte

doi:10.1002/anie.200460398

Allosterically driven multicomponent assembly

Pall Thordarson, Ruud G.E. Coumans, Johannes A.A.W. Elemans, Johan Visser, Paul J. Thomassen, Alan E. Rowan, Roeland J.M. Nolte

Onderzoeksoutput: Article › Academic › peer review

Samenvatting

Bound to cooperate: Binding of dimethylviologen in the cavity of a Zn porphyrin host dramatically increases the affinity of the host for N-donating ligands and vice versa (see scheme). These positive heterotropic allosteric effects are exploited to direct complex equilibrium mixtures towards a single self-assembled species. This allosteric magnification was used to obtain a pentameric sandwich architecture from a complex mixture of components.

Originele taal-2	English
Pagina's (van-tot)	4755-4759
Aantal pagina's	5
Tijdschrift	Angewandte Chemie International Edition
Volume	43
Nummer van het tijdschrift	36
DOI's	https://doi.org/10.1002/anie.200460398
Status	Published - 7 sep. 2004
Extern gepubliceerd	Ja

Keywords

allosteric effects
dimethylviologen
chemical compounds
multicomponents

Toegang tot document

10.1002/anie.200460398

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Kistemaker, J. C. M., Štacko, P., Roke, D., Wolters, A. T., Heideman, H., Chang, M.-C., Van der Meulen, P., Visser, J., Otten, E. & Feringa, B. L., 19 jul. 2017, In: Journal of the American Chemical Society. 139, 28, blz. 9650 - 9661 12 blz.
Onderzoeksoutput: Article › Academic › peer review

Open Access
From chaos to order: Chain-length dependence of the free energy of formation of meso-tetraalkylporphyrin self-assembled monolayer polymorphs
Reimers, J. R., Panduwinata, D., Visser, J., Chin, Y., Tang, C., Goerigk, L., Ford, M. J., Baker, M., Sum, T.-J., Coenen, M. J. J., Hendriksen, B. L. M., Elemans, J. A. A. W., Hush, N. S. & Crossley, M. J., 5 jan. 2016, In: Journal of Physical Chemistry C. 120, 3, blz. 1739 - 1748 10 blz.
Onderzoeksoutput: Article › Academic › peer review

Open Access
A priori calculations of the free energy of formation from solution of polymorphic self-Assembled monolayers
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Onderzoeksoutput: Article › Academic › peer review

Open Access

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9 okt. 2018
Activiteit: Oral presentation

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Visser, J. & Heeres, A.
17/09/20
1 item van Media-aandacht
Pers / media: Research

Citeer dit

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title = "Allosterically driven multicomponent assembly",

abstract = "Bound to cooperate: Binding of dimethylviologen in the cavity of a Zn porphyrin host dramatically increases the affinity of the host for N-donating ligands and vice versa (see scheme). These positive heterotropic allosteric effects are exploited to direct complex equilibrium mixtures towards a single self-assembled species. This allosteric magnification was used to obtain a pentameric sandwich architecture from a complex mixture of components.",

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doi = "10.1002/anie.200460398",

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T1 - Allosterically driven multicomponent assembly

AU - Thordarson, Pall

AU - Coumans, Ruud G.E.

AU - Elemans, Johannes A.A.W.

AU - Visser, Johan

AU - Thomassen, Paul J.

AU - Rowan, Alan E.

AU - Nolte, Roeland J.M.

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KW - chemische verbindingen

KW - multicomponenten

KW - allosteric effects

KW - dimethylviologen

KW - chemical compounds

KW - multicomponents

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DO - 10.1002/anie.200460398

M3 - Article

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JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 36

ER -

Allosterically driven multicomponent assembly

Samenvatting

Keywords

Toegang tot document

Vingerafdruk

Onderzoekersoutput

Third-Generation Light-Driven Symmetric Molecular Motors

From chaos to order: Chain-length dependence of the free energy of formation of meso-tetraalkylporphyrin self-assembled monolayer polymorphs

A priori calculations of the free energy of formation from solution of polymorphic self-Assembled monolayers

Activiteiten

Electrosynthesis of furans from grass

Pers/Media

Hooi als basis voor plastic

Citeer dit