Lewis-acid catalysis of carbon carbon bond forming reactions in water

Jan B.F.N. Engberts; Ben L. Feringa; Erik Keller; Sijbren Otto

doi:10.1002/recl.19961151103

Lewis-acid catalysis of carbon carbon bond forming reactions in water

Jan B.F.N. Engberts, Ben L. Feringa, Erik Keller, Sijbren Otto

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Abstract

In this article, we review the recent progress that has been made in the field of Lewis-acid catalysis of carbon carbon-bond-forming reactions in aqueous solution. Since water hampers the hard hard interactions between the catalyst and the reactant, it often complicates catalysis. However, once coordination has taken place, water can have beneficial effects on rates and selectivities of Lewis acid catalysed Diels Alder reactions, aldol reactions, allylation reactions, Barbier and Mannich type reactions as well as Michael additions.

Original language	English
Pages (from-to)	457-464
Journal	Recueil des travaux chimiques des Pays-Bas : journal of the Royal Netherlands Chemical Society
Volume	115
Issue number	11-12
DOIs	https://doi.org/10.1002/recl.19961151103
Publication status	Published - 1 Jan 1996

Keywords

lewis-acid catalysis
reactions in water

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10.1002/recl.19961151103

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AU - Keller, Erik

AU - Otto, Sijbren

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AB - In this article, we review the recent progress that has been made in the field of Lewis-acid catalysis of carbon carbon-bond-forming reactions in aqueous solution. Since water hampers the hard hard interactions between the catalyst and the reactant, it often complicates catalysis. However, once coordination has taken place, water can have beneficial effects on rates and selectivities of Lewis acid catalysed Diels Alder reactions, aldol reactions, allylation reactions, Barbier and Mannich type reactions as well as Michael additions.

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ER -

Lewis-acid catalysis of carbon carbon bond forming reactions in water

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Keywords

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