Allosterically driven multicomponent assembly

Pall Thordarson; Ruud G.E. Coumans; Johannes A.A.W. Elemans; Johan Visser; Paul J. Thomassen; Alan E. Rowan; Roeland J.M. Nolte

doi:10.1002/anie.200460398

Allosterically driven multicomponent assembly

Pall Thordarson, Ruud G.E. Coumans, Johannes A.A.W. Elemans, Johan Visser, Paul J. Thomassen, Alan E. Rowan, Roeland J.M. Nolte

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Bound to cooperate: Binding of dimethylviologen in the cavity of a Zn porphyrin host dramatically increases the affinity of the host for N-donating ligands and vice versa (see scheme). These positive heterotropic allosteric effects are exploited to direct complex equilibrium mixtures towards a single self-assembled species. This allosteric magnification was used to obtain a pentameric sandwich architecture from a complex mixture of components.

Original language	English
Pages (from-to)	4755-4759
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	43
Issue number	36
DOIs	https://doi.org/10.1002/anie.200460398
Publication status	Published - 7 Sept 2004
Externally published	Yes

Keywords

allosterische effecten
dimethylviologen
chemische verbindingen
multicomponenten

Access to Document

10.1002/anie.200460398

7 Article

Third-Generation Light-Driven Symmetric Molecular Motors
Kistemaker, J. C. M., Štacko, P., Roke, D., Wolters, A. T., Heideman, H., Chang, M.-C., Van der Meulen, P., Visser, J., Otten, E. & Feringa, B. L., 19 Jul 2017, In: Journal of the American Chemical Society. 139, 28, p. 9650 - 9661 12 p.
Research output: Contribution to journal › Article › Academic › peer-review

Open Access
From chaos to order: Chain-length dependence of the free energy of formation of meso-tetraalkylporphyrin self-assembled monolayer polymorphs
Reimers, J. R., Panduwinata, D., Visser, J., Chin, Y., Tang, C., Goerigk, L., Ford, M. J., Baker, M., Sum, T.-J., Coenen, M. J. J., Hendriksen, B. L. M., Elemans, J. A. A. W., Hush, N. S. & Crossley, M. J., 5 Jan 2016, In: Journal of Physical Chemistry C. 120, 3, p. 1739 - 1748 10 p.
Research output: Contribution to journal › Article › Academic › peer-review

Open Access
A priori calculations of the free energy of formation from solution of polymorphic self-Assembled monolayers
Reimers, J. R., Panduwinata, D., Visser, J., Tang, C., Goerigk, L., Ford, M. J., Sintic, M., Sum, T.-J., Coenen, M. J. J., Hendriksen, B. L. M., Elemans, J. A. A. W., Hush, N. S. & Crossley, M. J., 28 Oct 2015, In: Proceedings of the National Academy of Sciences. 112, 45, p. E6101 - E6110 10 p.
Research output: Contribution to journal › Article › Academic › peer-review

Open Access

1 Oral presentation

Electrosynthesis of furans from grass
Visser, J. (Speaker)
9 Oct 2018
Activity: Talk or presentation › Oral presentation

Hooi als basis voor plastic
Visser, J. & Heeres, A.
17/09/20
1 item of Media coverage
Press/Media: Research

Cite this

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title = "Allosterically driven multicomponent assembly",

abstract = "Bound to cooperate: Binding of dimethylviologen in the cavity of a Zn porphyrin host dramatically increases the affinity of the host for N-donating ligands and vice versa (see scheme). These positive heterotropic allosteric effects are exploited to direct complex equilibrium mixtures towards a single self-assembled species. This allosteric magnification was used to obtain a pentameric sandwich architecture from a complex mixture of components.",

keywords = "allosterische effecten, dimethylviologen, chemische verbindingen, multicomponenten, allosteric effects, dimethylviologen, chemical compounds, multicomponents",

author = "Pall Thordarson and Coumans, \{Ruud G.E.\} and Elemans, \{Johannes A.A.W.\} and Johan Visser and Thomassen, \{Paul J.\} and Rowan, \{Alan E.\} and Nolte, \{Roeland J.M.\}",

year = "2004",

month = sep,

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doi = "10.1002/anie.200460398",

language = "English",

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pages = "4755--4759",

journal = "Angewandte Chemie International Edition",

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T1 - Allosterically driven multicomponent assembly

AU - Thordarson, Pall

AU - Coumans, Ruud G.E.

AU - Elemans, Johannes A.A.W.

AU - Visser, Johan

AU - Thomassen, Paul J.

AU - Rowan, Alan E.

AU - Nolte, Roeland J.M.

PY - 2004/9/7

Y1 - 2004/9/7

N2 - Bound to cooperate: Binding of dimethylviologen in the cavity of a Zn porphyrin host dramatically increases the affinity of the host for N-donating ligands and vice versa (see scheme). These positive heterotropic allosteric effects are exploited to direct complex equilibrium mixtures towards a single self-assembled species. This allosteric magnification was used to obtain a pentameric sandwich architecture from a complex mixture of components.

AB - Bound to cooperate: Binding of dimethylviologen in the cavity of a Zn porphyrin host dramatically increases the affinity of the host for N-donating ligands and vice versa (see scheme). These positive heterotropic allosteric effects are exploited to direct complex equilibrium mixtures towards a single self-assembled species. This allosteric magnification was used to obtain a pentameric sandwich architecture from a complex mixture of components.

KW - allosterische effecten

KW - dimethylviologen

KW - chemische verbindingen

KW - multicomponenten

KW - allosteric effects

KW - dimethylviologen

KW - chemical compounds

KW - multicomponents

U2 - 10.1002/anie.200460398

DO - 10.1002/anie.200460398

M3 - Article

SN - 1433-7851

VL - 43

SP - 4755

EP - 4759

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 36

ER -

Allosterically driven multicomponent assembly

Abstract

Keywords

Access to Document

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Research output

Third-Generation Light-Driven Symmetric Molecular Motors

From chaos to order: Chain-length dependence of the free energy of formation of meso-tetraalkylporphyrin self-assembled monolayer polymorphs

A priori calculations of the free energy of formation from solution of polymorphic self-Assembled monolayers

Activities

Electrosynthesis of furans from grass

Press/Media

Hooi als basis voor plastic

Cite this