Research output per year
Research output per year
Abstract
Bound to cooperate: Binding of dimethylviologen in the cavity of a Zn porphyrin host dramatically increases the affinity of the host for N-donating ligands and vice versa (see scheme). These positive heterotropic allosteric effects are exploited to direct complex equilibrium mixtures towards a single self-assembled species. This allosteric magnification was used to obtain a pentameric sandwich architecture from a complex mixture of components.
| Original language | English |
|---|---|
| Pages (from-to) | 4755-4759 |
| Number of pages | 5 |
| Journal | Angewandte Chemie International Edition |
| Volume | 43 |
| Issue number | 36 |
| DOIs | |
| Publication status | Published - 7 Sept 2004 |
| Externally published | Yes |
Keywords
- allosterische effecten
- dimethylviologen
- chemische verbindingen
- multicomponenten
Fingerprint
Dive into the research topics of 'Allosterically driven multicomponent assembly'. Together they form a unique fingerprint.Research output
- 5 Article
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Third-Generation Light-Driven Symmetric Molecular Motors
Kistemaker, J. C. M., Štacko, P., Roke, D., Wolters, A. T., Heideman, H., Chang, M-C., Van der Meulen, P., Visser, J., Otten, E. & Feringa, B. L., 19 Jul 2017, In: Journal of the American Chemical Society. 139, 28, p. 9650 - 9661 12 p.Research output: Contribution to journal › Article › Academic › peer-review
Open Access -
From chaos to order: Chain-length dependence of the free energy of formation of meso-tetraalkylporphyrin self-assembled monolayer polymorphs
Reimers, J. R., Panduwinata, D., Visser, J., Chin, Y., Tang, C., Goerigk, L., Ford, M. J., Baker, M., Sum, T-J., Coenen, M. J. J., Hendriksen, B. L. M., Elemans, J. A. A. W., Hush, N. S. & Crossley, M. J., 5 Jan 2016, In: Journal of Physical Chemistry C. 120, 3, p. 1739 - 1748 10 p.Research output: Contribution to journal › Article › Academic › peer-review
Open Access -
A priori calculations of the free energy of formation from solution of polymorphic self-Assembled monolayers
Reimers, J. R., Panduwinata, D., Visser, J., Tang, C., Goerigk, L., Ford, M. J., Sintic, M., Sum, T-J., Coenen, M. J. J., Hendriksen, B. L. M., Elemans, J. A. A. W., Hush, N. S. & Crossley, M. J., 28 Oct 2015, In: Proceedings of the National Academy of Sciences. 112, 45, p. E6101 - E6110 10 p.Research output: Contribution to journal › Article › Academic › peer-review
Open Access
Activities
- 1 Oral presentation
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Electrosynthesis of furans from grass
Johan Visser (Speaker)
9 Oct 2018Activity: Talk or presentation › Oral presentation